Maybe pour the coffer grounds around tomatoes and other acid soil plants if
your soil has a higher pH. Ring plants a little further away if they are
pestered with slugs or land snails with coffee grounds. The little beggars
don't like the stuff. (Coffee nerves?)
This according to a buddy (also a fish head) who gardens.
In fact, I would love to install a cheap sink in the fish room, run a pipe
through the wall, and send water changed out from tanks through the sink and
a hose to garden spots much in need of water and nutrients.
As for the worms, plain old hardwood leaves are great. Somebody even
suggested them for blackworms.
All the best...
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